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Bis[?-1,1'-(ferrocene-1,1'-di-yl)bis(butane-1,3-dionato)]di-?-methanol-diiron(II).

ABSTRACT: The asymmetric unit of the title compound, [Fe(4)(C(9)H(8)O(2))(4)(CH(3)OH)(2)], contains one half-mol-ecule located on a twofold rotational axis. In the mol-ecule, the two Fe(II) ions bridged by two coordinating methanol mol-ecules are separated by 3.1286?(7)?Å. Two crystallographically independent methanol mol-ecules are situated on a twofold rotational axis; all attached H atoms are rotationally disordered between two equal orientations.

SUBMITTER: Xiao YF

PROVIDER: S-EPMC2969521 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis[μ-1,1'-(ferrocene-1,1'-di-yl)bis(butane-1,3-dionato)]di-μ-methanol-diiron(II).

Xiao Yan-Feng YF Li Hong-Feng HF Yan Peng-Fei PF Li Guang-Ming GM

Acta crystallographica. Section E, Structure reports online 20090507 Pt 6

The asymmetric unit of the title compound, [Fe(4)(C(9)H(8)O(2))(4)(CH(3)OH)(2)], contains one half-mol-ecule located on a twofold rotational axis. In the mol-ecule, the two Fe(II) ions bridged by two coordinating methanol mol-ecules are separated by 3.1286 (7) Å. Two crystallographically independent methanol mol-ecules are situated on a twofold rotational axis; all attached H atoms are rotationally disordered between two equal orientations. ...[more]

PMID: 21582994

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