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N,N'-Bis-[(E)-(6-methyl-2-pyridyl)-methyl-ene]hexane-1,6-diamine.

ABSTRACT: The title compound, C(20)H(26)N(4), is composed of two (6-methyl-2-pyridyl)methyl-ene units linked by a 1,6-diamine hexane chain. The mol-ecule has C(i) symmetry with the inversion center situated at the mid-point of the central C-C bond. The alkyl chain has an all-trans conformation, with all the non-H atoms sharing the same plane [maximum deviation 0.004?(3)?Å]. The pyridylmethyl-ene groups are also planar [maximum deviation 0.009?(3)?Å], making an angle of 53.78?(19)° with the hexane chain plane. In the crystal, the mol-ecules assemble in layers, stacking along the a axis. The stacks are hold together by attractive interactions between ? electron systems.

SUBMITTER: Ramos Silva M 

PROVIDER: S-EPMC2969618 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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N,N'-Bis-[(E)-(6-methyl-2-pyridyl)-methyl-ene]hexane-1,6-diamine.

Ramos Silva Manuela M   Silva Joana A JA   Matos Beja Ana A   Sobral Abilio J F N AJ  

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

The title compound, C(20)H(26)N(4), is composed of two (6-methyl-2-pyridyl)methyl-ene units linked by a 1,6-diamine hexane chain. The mol-ecule has C(i) symmetry with the inversion center situated at the mid-point of the central C-C bond. The alkyl chain has an all-trans conformation, with all the non-H atoms sharing the same plane [maximum deviation 0.004 (3) Å]. The pyridylmethyl-ene groups are also planar [maximum deviation 0.009 (3) Å], making an angle of 53.78 (19)° with the hexane chain pl  ...[more]

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