Unknown

Dataset Information

0

Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-?N,N',O]manganese(II) dihydrate.

ABSTRACT: The title complex, [Mn(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, is isotypic with the previously reported Zn(II) and Cd(II) species. The complex was prepared by the reaction of the potassium salt of 2-(2-pyridylmethyl-eneamino)benzene-sulfonic acid with MnCl(2)·6H(2)O in methanol. The complex displays twofold symmetry, with the ligands coordinated in a tridentate meridional-like arrangement through pyridyl N, imine N, and sulfonate O atoms. The metal center has a strongly distorted octa-hedral coordination geometry. The uncoordin-ated water mol-ecules and the complexes participate in a hydrogen-bonding network, forming a two-dimensional structure parallel to the ab plane.

SUBMITTER: Zhao CQ 

PROVIDER: S-EPMC2969898 | biostudies-other | 2009

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-κN,N',O]manganese(II) dihydrate.

Zhao Cheng-Qiang CQ   Ou-Yang Miao M   Huang Xue-Ren XR   Jiang Yi-Min YM  

Acta crystallographica. Section E, Structure reports online 20090808 Pt 9

The title complex, [Mn(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, is isotypic with the previously reported Zn(II) and Cd(II) species. The complex was prepared by the reaction of the potassium salt of 2-(2-pyridylmethyl-eneamino)benzene-sulfonic acid with MnCl(2)·6H(2)O in methanol. The complex displays twofold symmetry, with the ligands coordinated in a tridentate meridional-like arrangement through pyridyl N, imine N, and sulfonate O atoms. The metal center has a strongly distorted octa-hedral coordinatio  ...[more]

Similar Datasets

Unknown Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-?N,N',O]cobalt(II) dihydrate.
| S-EPMC2971130 | biostudies-literature
Unknown Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-?N,N',O]zinc(II) dihydrate.
| S-EPMC2960510 | biostudies-literature
Unknown Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-?N,N',O]cadmium(II) dihydrate.
| S-EPMC2959732 | biostudies-literature
Unknown Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato]-?N,N',O;?N,N'-copper(II).
| S-EPMC2970261 | biostudies-literature
Unknown 1,4-Bis(3-pyridylmethyl-eneamino-meth-yl)benzene.
| S-EPMC2968309 | biostudies-literature
Unknown 2,3,5,6-Tetra-fluoro-1,4-bis-(2-pyridylmethyl-eneamino-meth-yl)benzene.
| S-EPMC2968251 | biostudies-literature
Unknown Bis(4-amino-benzene-sulfonato-?N)diaqua-bis(dimethyl-formamide-?O)nickel(II) dihydrate.
| S-EPMC2969510 | biostudies-literature
Unknown Tetra-aqua-bis[2-(thio-semi-carbazono-methyl)benzene-sulfonato]manganese(II).
| S-EPMC2971282 | biostudies-literature
Unknown Bis(4-amino-benzene-sulfonato-?O)bis-(propane-1,3-diamine-?N,N')copper(II) dihydrate.
| S-EPMC2972104 | biostudies-literature
Unknown Tris[4-(2-pyridylmethyl-eneamino)phenol]iron(II) bis-(perchlorate).
| S-EPMC2915141 | biostudies-literature