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(E)-Methyl N'-(3-methoxy-benzyl-idene)hydrazinecarboxyl-ate.


ABSTRACT: The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol-ecules in the asymmetric unit which differ in the orientation of the meth-oxy group. Each independent mol-ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol-ecules are linked into chains running along [001] by N-H?O and N-H?N hydrogen bonds. In addition, an inter-molecular C-H?? inter-action is observed.

SUBMITTER: Lv LP 

PROVIDER: S-EPMC2970081 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(E)-Methyl N'-(3-methoxy-benzyl-idene)hydrazinecarboxyl-ate.

Lv Lu-Ping LP   Yu Wen-Bo WB   Huang Chun-Yu CY   Li Wei-Wei WW   Hu Xian-Chao XC  

Acta crystallographica. Section E, Structure reports online 20090826 Pt 9


The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol-ecules in the asymmetric unit which differ in the orientation of the meth-oxy group. Each independent mol-ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol-ecules are linked into chains running along [001] by N-H⋯O and N-H⋯N hydrogen bonds. In addition, an inter-molecular C-H⋯π inter-action is observed. ...[more]

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