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Trans-(Pyrimidine-2-thiol-ato-?N,S)[tris-(2-amino-ethyl)amine-?N,N',N'',N''']cobalt(III) chloride hexa-fluoridophosphate.

ABSTRACT: In the title compound, [Co(C(4)H(3)N(2)S)(C(6)H(18)N(4))](Cl)PF(6), the Co(III) ion is coordinated by a tripod-like tetra-dentate ligand and a monoanionic N,S-bidentate ligand in an approximately octa-hedral CoN(4)OS geometry. The anionic S atom of the pyrimidine-2-thiol-ate (pymt) ligand is coordinated in the trans position to the primary amine N atom (Nprim) of the tris-(2-amino-ethyl)amine (tren) ligand. The crystal structure exhibits short inter-molecular N-H?N hydrogen bonds (N?N <3.2?Å), and inter-molecular N-H?Cl and C-H?F contacts, leading to the formation of an infinite two-dimensional network.

SUBMITTER: Fujihara K

PROVIDER: S-EPMC2970082 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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trans-(Pyrimidine-2-thiol-ato-κN,S)[tris-(2-amino-ethyl)amine-κN,N',N'',N''']cobalt(III) chloride hexa-fluoridophosphate.

Fujihara Keisuke K Yonemura Toshiaki T

Acta crystallographica. Section E, Structure reports online 20090822 Pt 9

In the title compound, [Co(C(4)H(3)N(2)S)(C(6)H(18)N(4))](Cl)PF(6), the Co(III) ion is coordinated by a tripod-like tetra-dentate ligand and a monoanionic N,S-bidentate ligand in an approximately octa-hedral CoN(4)OS geometry. The anionic S atom of the pyrimidine-2-thiol-ate (pymt) ligand is coordinated in the trans position to the primary amine N atom (Nprim) of the tris-(2-amino-ethyl)amine (tren) ligand. The crystal structure exhibits short inter-molecular N-H⋯N hydrogen bonds (N⋯N <3.2 Å), a ...[more]

PMID: 21577467

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