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Bis[2,6-bis-(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis-(per-chlorate) acetonitrile solvate.

ABSTRACT: In the cation of the title compound, [Mn(C(11)H(13)N(5))(2)](ClO(4))(2)·CH(3)CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis-(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of the perchlorate anions are disordered with occupancies in the ratio 0.593?(10):0.407?(10). In the crystal, mol-ecules are stabilized by two N-H?O hydrogen bonds, forming zigzag chains along the a axis, which are further inter-connected by N-H?O hydrogen bonds and ?-? inter-actions [centroid-centroid distance = 3.50?(1)?Å] into a three-dimensional network.

SUBMITTER: Shang SM 

PROVIDER: S-EPMC2970088 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis[2,6-bis-(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis-(per-chlorate) acetonitrile solvate.

Shang Shao-Ming SM   Ren Chun-Xia CX   Wang Xin X   Lu Lu-De LD   Yang Xu-Jie XJ  

Acta crystallographica. Section E, Structure reports online 20090808 Pt 9

In the cation of the title compound, [Mn(C(11)H(13)N(5))(2)](ClO(4))(2)·CH(3)CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis-(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of the perchlorate anions are disordered with occupancies in the ratio 0.593 (10):0.407 (10). In the crystal, mol-ecules are stabilized by two N-H⋯O hydrogen bonds, forming zigzag chains along the a a  ...[more]

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