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Catena-Poly[copper(II)-di-?-dicyan-amido-?-1,3-di-4-pyridylpropane].

ABSTRACT: In the title compound, [Cu(C(2)N(3))(2)(C(13)H(14)N(2))](n), the Cu(II) atom, located on an inversion centre, adopts a distorted octa-hedral coordination by six N atoms, two from 1,3-di-4-pyridylpropane and four from dicyanamide ligands, with significantly different Cu-N distances. The metal centres are linked in an unusual triple-bridged mode into chains parallel to [101].

SUBMITTER: Zhang J

PROVIDER: S-EPMC2970089 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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catena-Poly[copper(II)-di-μ-dicyan-amido-μ-1,3-di-4-pyridylpropane].

Zhang Jinfang J

Acta crystallographica. Section E, Structure reports online 20090808 Pt 9

In the title compound, [Cu(C(2)N(3))(2)(C(13)H(14)N(2))](n), the Cu(II) atom, located on an inversion centre, adopts a distorted octa-hedral coordination by six N atoms, two from 1,3-di-4-pyridylpropane and four from dicyanamide ligands, with significantly different Cu-N distances. The metal centres are linked in an unusual triple-bridged mode into chains parallel to [101]. ...[more]

PMID: 21577406

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catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κN:N'].

Project description:In the title compound, [CoCl(2)(C(13)H(14)N(2))](n), 1,3-bis-(4-pyrid-yl)propane (bpp) ligands bridge four-coordinate Co atoms, generating an extended one-dimensional zigzag chain. Both the Co and two Cl atoms in the tetrahedral coordination polyhedron lie on a mirror plane, while the bbp ligand is bis-ected through the central C atom in the chain by a second mirror plane. There are some π-π stacking inter-ations in the crystal structure, with inter-planar distances of 3.449 Å, which are responsible for the supra-molecular assembly.

| S-EPMC2961947 | biostudies-literature

catena-Poly[[dichloridonickel(II)]-?-1,3-di-4-pyridylpropane].

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catena-Poly[[bis-(4-methyl-benzene-thiol-ato)cadium(II)]-μ-1,3-di-4-pyridylpropane].

Project description:In the title compound, [Cd(C(7)H(7)S)(2)(C(13)H(14)N(2))](n), the unique Cd(II) ion, located on a twofold rotation axis, is coordinated by two S atoms and two N atoms in a slightly distorted tetra-hedral environment. Symmetry-related Cd(II) ions are linked via bridging 1,3-di-4-pyridylpropane ligands, forming a zig-zag chain-structure parallel to [001]. In the crystal structure, there are weak intra-chain π-π stacking inter-actions between benzene rings, with a centroid-centroid distance of 3.825 (7) Å, and pairs of chains are inter-digitated with respect to the 4-methyl-benzene-thiol-ate groups.

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catena-Poly[[bis-(3-carb-oxy-5-nitro-benzoato-?O)copper(II)]-?-1,3-di-4-pyridylpropane-?N:N'].

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catena-Poly[[[aqua-(pyridine-2,6-dicarboxyl-ato N-oxide-?O,O)cobalt(II)]-?-1,3-di-4-pyridylpropane-?N:N'] dihydrate].

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Poly[?(2)-benzene-1,3-dicarboxyl-ato-?O:O'-?(2)-1,3-di-4-pyridylpropane-?N:N'-zinc(II)].

Project description:The title compound, [Zn(C(8)H(4)O(4))(C(13)H(14)N(2))](n), was obtained by the hydro-thermal reaction of Zn(OAc)(2)·H(2)O with 1,3-di-4-pyridylpropane (bpp) and isophthalic acid (H(2)ip). The Zn(II) ion is coordinated by two bpp and two ip ligands in a distorted tetra-hedral environment. Each ligand coordinates in a bridging mode to connect Zn(II) ions into a three-dimensional diamondoid-type structure.

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Poly[di-?(2)-chlorido(?(2)-1,3-di-4-pyridylpropane-?N:N')lead(II)].

Project description:The title Pb(II) coordination polymer, [PbCl(2)(C(13)H(14)N(2))], was prepared by the hydro-thermal reaction of PbCl(2) with 4,4,-trimethyl-enedipyridine in a 1:1 ratio. It exhibits a two-dimensional layered structural motif consisting of PbCl(2) chains and the flexible bridged 4,4'-trimethyl-enedipyridine ligand. The connections result in a cavity of about 4 × 15?Å.

| S-EPMC2970293 | biostudies-other

Crystal structure of catena-poly[1,3-di-benzyl-benzimidazolium [[chlorido-mercurate(II)]-di-?-chlorido]].

Project description:The asymmetric unit of the polymeric title compound, {(C21H19N2)[HgCl3]} n , comprises one-half of the cationic mol-ecule, the other half being generated by application of twofold rotation symmetry, one Hg and two Cl atoms. The Hg(II) atom, lying on a twofold rotation axis, exhibits a distorted triangular coordination environment and is surrounded by three Cl atoms with Hg-Cl distances in the range 2.359?(2)-2.4754?(13)?Å. Two additional longer distances [Hg?Cl = 3.104?(14)?Å] lead to the formation of polymeric [HgCl1/1Cl4/2](-) chains extending along [001]. The crystal packing can be described by cationic layers alternating parallel to (-110) with the anionic chains located between the layers. The packing is consolidated by ?-? stacking inter-actions between the benzene rings of the central benzimidazole entities, with centroid-to-centroid distances of 3.643?(3)?Å.

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