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Catena-Poly[copper(II)-di-?-dicyan-amido-?-1,3-di-4-pyridylpropane].


ABSTRACT: In the title compound, [Cu(C(2)N(3))(2)(C(13)H(14)N(2))](n), the Cu(II) atom, located on an inversion centre, adopts a distorted octa-hedral coordination by six N atoms, two from 1,3-di-4-pyridylpropane and four from dicyanamide ligands, with significantly different Cu-N distances. The metal centres are linked in an unusual triple-bridged mode into chains parallel to [101].

SUBMITTER: Zhang J 

PROVIDER: S-EPMC2970089 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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catena-Poly[copper(II)-di-μ-dicyan-amido-μ-1,3-di-4-pyridylpropane].

Zhang Jinfang J  

Acta crystallographica. Section E, Structure reports online 20090808 Pt 9


In the title compound, [Cu(C(2)N(3))(2)(C(13)H(14)N(2))](n), the Cu(II) atom, located on an inversion centre, adopts a distorted octa-hedral coordination by six N atoms, two from 1,3-di-4-pyridylpropane and four from dicyanamide ligands, with significantly different Cu-N distances. The metal centres are linked in an unusual triple-bridged mode into chains parallel to [101]. ...[more]

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