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Bis[4-chloro-2-(imino-meth-yl)phenolato]copper(II) methanol disolvate.

ABSTRACT: The title compound, [Cu(C(7)H(5)ClNO)(2)]·2CH(3)OH, possesses crystallographic twofold symmetry, with the twofold axis passing through the central Cu(II) ion. The metal centre is coordinated by two O atoms and two N atoms from two symmetry-related Schiff base ligands, forming a slightly distorted cis-CuN(2)O(2) square-planar geometry. The complex mol-ecules are linked via the solvent methanol mol-ecules by O-H?O and N-H?O hydrogen bonds, leading to the formation of chains along the b axis.

SUBMITTER: Qin B 

PROVIDER: S-EPMC2970101 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis[4-chloro-2-(imino-meth-yl)phenolato]copper(II) methanol disolvate.

Qin Bei B  

Acta crystallographica. Section E, Structure reports online 20090819 Pt 9

The title compound, [Cu(C(7)H(5)ClNO)(2)]·2CH(3)OH, possesses crystallographic twofold symmetry, with the twofold axis passing through the central Cu(II) ion. The metal centre is coordinated by two O atoms and two N atoms from two symmetry-related Schiff base ligands, forming a slightly distorted cis-CuN(2)O(2) square-planar geometry. The complex mol-ecules are linked via the solvent methanol mol-ecules by O-H⋯O and N-H⋯O hydrogen bonds, leading to the formation of chains along the b axis. ...[more]

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