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Cis-Dichloridobis(triphenyl-phosphine-?P)platinum(II) chloro-form solvate.

ABSTRACT: In the title compound, [PtCl(2)(C(18)H(15)P)(2)]·CHCl(3), each Pt(II) centre adopts a nearly square-planar coordination geometry formed by two P atoms [Pt-P = 2.2481?(17) and 2.2658?(19)?Å] and two Cl anions [Pt-Cl = 2.3244?(19) and 2.3548?(17)?Å]. The Cl atoms of the chloro-form solvent mol-ecule are disordered over two orientations in a 0.778?(11):0.222?(11) ratio. The crystal packing is stabilized by weak inter-molecular C-H?Cl hydrogen bonds, exhib-iting voids with a volume of 215?Å(3).

SUBMITTER: Miao J

PROVIDER: S-EPMC2970157 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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cis-Dichloridobis(triphenyl-phosphine-κP)platinum(II) chloro-form solvate.

Miao Jinling J Hu Chunhua C Feng Xiao X Chen Hongwei H Nie Yong Y

Acta crystallographica. Section E, Structure reports online 20090808 Pt 9

In the title compound, [PtCl(2)(C(18)H(15)P)(2)]·CHCl(3), each Pt(II) centre adopts a nearly square-planar coordination geometry formed by two P atoms [Pt-P = 2.2481 (17) and 2.2658 (19) Å] and two Cl anions [Pt-Cl = 2.3244 (19) and 2.3548 (17) Å]. The Cl atoms of the chloro-form solvent mol-ecule are disordered over two orientations in a 0.778 (11):0.222 (11) ratio. The crystal packing is stabilized by weak inter-molecular C-H⋯Cl hydrogen bonds, exhib-iting voids with a volume of 215 Å(3). ...[more]

PMID: 21577392

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