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1-Bromo-1'-(diphenyl-thio-phosphor-yl)-ferrocene.


ABSTRACT: The title compound, [Fe(C(5)H(4)Br)(C(17)H(14)PS)], crystallizes with two practically undistiguishable mol-ecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1'-diyl units exhibit a regular geometry with negligible tilting and balanced Fe-ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed.

SUBMITTER: Stepnicka P 

PROVIDER: S-EPMC2970171 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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1-Bromo-1'-(diphenyl-thio-phosphor-yl)-ferrocene.

Stěpnička Petr P   Schulz Jiří J   Císařová Ivana I  

Acta crystallographica. Section E, Structure reports online 20090912 Pt 10


The title compound, [Fe(C(5)H(4)Br)(C(17)H(14)PS)], crystallizes with two practically undistiguishable mol-ecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1'-diyl units exhibit a regular geometry with negligible tilting and balanced Fe-ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed. ...[more]

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