4-(2-Methyl-piperidin-1-ylcarbon-yl)pyridinium hexachloridoantimonate(V).

ABSTRACT: In the hexa-chlorido-animonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octa-hedral coordination. In the 4-(2-methyl-piperidine-1-carbon-yl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 66.3?(3)°. The mean plane of the carbonyl group is twisted by 80.5?(7)° and 42.7?(4)° relative to the mean planes of the pyridine and piperzine rings, respectively. The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation. The crystal packing is stabilized by N-H?O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010].

SUBMITTER: Wang B 

PROVIDER: S-EPMC2970264 | biostudies-other | 2009

REPOSITORIES: biostudies-other