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2,4-Dichloro-N-p-tolyl-benzamide.

ABSTRACT: In the title compound, C(14)H(11)Cl(2)NO, the C-N-C(=O)-C amide unit is almost planar (r.m.s. deviation = 0.0317?Å) and subtends dihedral angles of 65.93?(6) and 29.45?(7)°, respectively, to the dichloro-benzene and tolyl rings. The two aromatic rings are inclined at 37.92?(6)° to one another. In the crystal structure, N-H?O hydrogen bonds link the mol-ecules into chains along b. Additional weak C-H?Cl and C-H?O hydrogen bonds combine with C-H?? and very weak ?-? contacts [Cg?Cg distance = 4.0217?(12)?Å] to stack the mol-ecules down b.

SUBMITTER: Saeed A

PROVIDER: S-EPMC2970402 | biostudies-other | 2009 Sep

REPOSITORIES: biostudies-other

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2,4-Dichloro-N-p-tolyl-benzamide.

Saeed Aamer A Khera Rasheed Ahmad RA Rafique Hummera H Simpson Jim J Stanley Roderick G RG

Acta crystallographica. Section E, Structure reports online 20090926 Pt 10

In the title compound, C(14)H(11)Cl(2)NO, the C-N-C(=O)-C amide unit is almost planar (r.m.s. deviation = 0.0317 Å) and subtends dihedral angles of 65.93 (6) and 29.45 (7)°, respectively, to the dichloro-benzene and tolyl rings. The two aromatic rings are inclined at 37.92 (6)° to one another. In the crystal structure, N-H⋯O hydrogen bonds link the mol-ecules into chains along b. Additional weak C-H⋯Cl and C-H⋯O hydrogen bonds combine with C-H⋯π and very weak π-π contacts [Cg⋯Cg distance = 4.021 ...[more]

PMID: 21577972

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