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Bis(tetra-phenyl-phospho-nium) tris-[N-(methyl-sulfon-yl)dithio-carbimato(2-)-?S,S']stannate(IV).

ABSTRACT: In the title complex, (C(24)H(20)P)(2)[Sn(C(2)H(3)NO(2)S(3))(3)], the Sn(IV) atom is coordinated by three N-(methyl-sulfon-yl)dithio-carbimate bidentate ligands through the anionic S atoms in a slightly distorted octa-hedral coordination geometry. There is one half-mol-ecule in the asymmetric unit; the complex is located on a crystallographic twofold rotation axis passing through the cation and bis-ecting one of the (non-symmetric) ligands, which appears thus disordered over two sites of equal occupancy. In the crystal structure, weak inter-molecular C-H?O and C-H?S inter-actions contribute to the packing stabilization.

SUBMITTER: Barolli JP

PROVIDER: S-EPMC2970435 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis(tetra-phenyl-phospho-nium) tris-[N-(methyl-sulfon-yl)dithio-carbimato(2-)-κS,S']stannate(IV).

Barolli João P JP Oliveira Marcelo R L MR Corrêa Rodrigo S RS Ellena Javier J

Acta crystallographica. Section E, Structure reports online 20090905 Pt 10

In the title complex, (C(24)H(20)P)(2)[Sn(C(2)H(3)NO(2)S(3))(3)], the Sn(IV) atom is coordinated by three N-(methyl-sulfon-yl)dithio-carbimate bidentate ligands through the anionic S atoms in a slightly distorted octa-hedral coordination geometry. There is one half-mol-ecule in the asymmetric unit; the complex is located on a crystallographic twofold rotation axis passing through the cation and bis-ecting one of the (non-symmetric) ligands, which appears thus disordered over two sites of equal o ...[more]

PMID: 21577695

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