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Dichlorido(2,9-diprop-oxy-1,10-phenanthroline-?N,N')cadmium(II).

ABSTRACT: In the title complex, [CdCl(2)(C(18)H(20)N(2)O(2))], the Cd(II) ion is coordinated by two N atoms from a bis-chelating 2,9-diprop-oxy-1,10-phenanthroline ligand and two Cl atoms in a distorted tetra-hedral environment. The two Cd-Cl bond distances are significantly different from each other and the N-Cd-N bond angle is acute. In the crystal structure, there are ?-? stacking inter-actions between symmetry-related phenanthroline ring systems, with a centroid-centroid distance of 3.585?(3)?Å.

SUBMITTER: Niu CY

PROVIDER: S-EPMC2970460 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Dichlorido(2,9-diprop-oxy-1,10-phenanthroline-κN,N')cadmium(II).

Niu Cao-Yuan CY Zheng Xian-Fu XF Dang Yu-Li YL

Acta crystallographica. Section E, Structure reports online 20090926 Pt 10

In the title complex, [CdCl(2)(C(18)H(20)N(2)O(2))], the Cd(II) ion is coordinated by two N atoms from a bis-chelating 2,9-diprop-oxy-1,10-phenanthroline ligand and two Cl atoms in a distorted tetra-hedral environment. The two Cd-Cl bond distances are significantly different from each other and the N-Cd-N bond angle is acute. In the crystal structure, there are π-π stacking inter-actions between symmetry-related phenanthroline ring systems, with a centroid-centroid distance of 3.585 (3) Å. ...[more]

PMID: 21577762

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