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(2-Acetyl-phenolato)(2,2'-bipyridine)nitratocopper(II).

ABSTRACT: In the title compound, [Cu(C(8)H(7)O(2))(NO(3))(C(10)H(8)N(2))], the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. The basal positions are occupied by two N atoms from a 2,2'-bipyridine ligand and two O atoms from the 2-acetyl-phenolate anion. The axial position is occupied by one O atom of a nitrate anion. In the bipyridine ligand, the two pyridine rings are slightly twisted by an angle of 3.5?(1)°. The crystal structure is stabilized by C-H?O hydrogen bonds.

SUBMITTER: Chen LH

PROVIDER: S-EPMC2971079 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(2-Acetyl-phenolato)(2,2'-bipyridine)nitratocopper(II).

Chen Li-Hua LH Zhao Gan-Qing GQ Wang Xiang X Peng Qin-Long QL Pan Zi-Hong ZH

Acta crystallographica. Section E, Structure reports online 20091023 Pt 11

In the title compound, [Cu(C(8)H(7)O(2))(NO(3))(C(10)H(8)N(2))], the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. The basal positions are occupied by two N atoms from a 2,2'-bipyridine ligand and two O atoms from the 2-acetyl-phenolate anion. The axial position is occupied by one O atom of a nitrate anion. In the bipyridine ligand, the two pyridine rings are slightly twisted by an angle of 3.5 (1)°. The crystal structure is stabilized by C-H⋯O hydrogen bonds. ...[more]

PMID: 21578163

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