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[2-Oxido-1-naphthaldehyde (2-hydroxy-benzo-yl)hydrazonato]diphenyl-tin(IV).

ABSTRACT: In the title compound, [Sn(C(6)H(5))(2)(C(18)H(12)N(2)O(3))], the Sn(IV) atom has a distorted trigonal-bipyramidal geometry. The Schiff base mol-ecule is coordinated to the Sn(IV) atom in a tridentate fashion via the azomethine N atom, the hydr-oxy O atom and the carbonyl O atom. The complex involves an intra-molecular O-H?N hydrogen bond.

SUBMITTER: Li J

PROVIDER: S-EPMC2971108 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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[2-Oxido-1-naphthaldehyde (2-hydroxy-benzo-yl)hydrazonato]diphenyl-tin(IV).

Li Jing J Yin Handong H Wen Liyuan L Cui Jichun J

Acta crystallographica. Section E, Structure reports online 20091028 Pt 11

In the title compound, [Sn(C(6)H(5))(2)(C(18)H(12)N(2)O(3))], the Sn(IV) atom has a distorted trigonal-bipyramidal geometry. The Schiff base mol-ecule is coordinated to the Sn(IV) atom in a tridentate fashion via the azomethine N atom, the hydr-oxy O atom and the carbonyl O atom. The complex involves an intra-molecular O-H⋯N hydrogen bond. ...[more]

PMID: 21578172

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{4-Hy-droxy-N'-[(2E,3Z)-4-oxido-4-phenyl-but-3-en-2-yl-idene]benzo-hydra-zidato}diphenyl-tin(IV) methanol monosolvate.

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(1,5-Diphenyl-thio-carbazonato-?S)trimethyl-tin(IV).

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