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[(3-Methylphenyl)(triphenylphosphonio)methanide-?C]triphenyl-phospho-rane}(penta-fluoro-phenyl-?C)gold(I) diethyl ether solvate.

ABSTRACT: The metal atom in the title ylid-gold(I) adduct, [Au(C(6)F(5))(C(26)H(23)P)]·C(4)H(10)O, exists in a linear coordination environment [C-Au-C = 174.1?(2)°]. The mol-ecule has a short intra-molecular contact involving an aromatic H atom (Au?H = 2.64?Å); two adjacent mol-ecules are linked by an Au?H(ylid) inter-action (Au?H = 3.14?Å).

SUBMITTER: Strasser CE

PROVIDER: S-EPMC2971244 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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[(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl-phospho-rane}(penta-fluoro-phenyl-κC)gold(I) diethyl ether solvate.

Strasser Christoph E CE Coetzee Karolien K Cronje Stephanie S Raubenheimer Helgard G HG

Acta crystallographica. Section E, Structure reports online 20091017 Pt 11

The metal atom in the title ylid-gold(I) adduct, [Au(C(6)F(5))(C(26)H(23)P)]·C(4)H(10)O, exists in a linear coordination environment [C-Au-C = 174.1 (2)°]. The mol-ecule has a short intra-molecular contact involving an aromatic H atom (Au⋯H = 2.64 Å); two adjacent mol-ecules are linked by an Au⋯H(ylid) inter-action (Au⋯H = 3.14 Å). ...[more]

PMID: 21578124

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