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Dibromido(6,6'-dimethyl-2,2'-bipyridine-?N,N')zinc(II).


ABSTRACT: In the title compound, [ZnBr(2)(C(12)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral arrangement by an N,N'-bidentate 6,6'-dimethyl-2,2'-bipyridine ligand and two bromide ions. In the crystal, there are aromatic ?-? contacts between the pyridine rings [centroid-centroid distances = 3.818?(3) and 3.728?(4)?Å].

SUBMITTER: Alizadeh R 

PROVIDER: S-EPMC2971289 | biostudies-other | 2009 Oct

REPOSITORIES: biostudies-other

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Dibromido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Alizadeh Robabeh R   Khoshtarkib Zeinab Z   Chegeni Katayoon K   Ebadi Amin A   Amani Vahid V  

Acta crystallographica. Section E, Structure reports online 20091007 Pt 11


In the title compound, [ZnBr(2)(C(12)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral arrangement by an N,N'-bidentate 6,6'-dimethyl-2,2'-bipyridine ligand and two bromide ions. In the crystal, there are aromatic π-π contacts between the pyridine rings [centroid-centroid distances = 3.818 (3) and 3.728 (4) Å]. ...[more]

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