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Bis[N-(2-pyridylcarbon-yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate.

ABSTRACT: In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl-carbon-yl)pyridine-2-carboximidate (bpca) ligands and exhib-its a distorted octa-hedral coordination by six bpca N atoms. A classical O-H?O hydrogen bond exists between the methanol solvent mol-ecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5-400?K.

SUBMITTER: Wu D

PROVIDER: S-EPMC2971300 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis[N-(2-pyridylcarbon-yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate.

Wu Dayu D

Acta crystallographica. Section E, Structure reports online 20091010 Pt 11

In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl-carbon-yl)pyridine-2-carboximidate (bpca) ligands and exhib-its a distorted octa-hedral coordination by six bpca N atoms. A classical O-H⋯O hydrogen bond exists between the methanol solvent mol-ecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5-400 K. ...[more]

PMID: 21578096

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