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Aqua-bis(benzoato-?O)(5,5'-dimethyl-2,2'-bipyridine-?N,N')copper(II).

ABSTRACT: In the crystal structure of the title compound, [Cu(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(H(2)O)], the Cu(II) ion is penta-coordinated in a distorted square-pyramidal geometry by two O atoms of two benzoate anions and two N atoms of a 5,5'-dimethyl-2,2'-bipyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O-H?O hydrogen bonds link the mol-ecules into a supra-molecular structure. The crystal studied was a racemic twin, as suggested by the Flack parameter of 0.584?(14).

SUBMITTER: Dong XY

PROVIDER: S-EPMC2971325 | biostudies-other | 2009 Oct

REPOSITORIES: biostudies-other

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Aqua-bis(benzoato-κO)(5,5'-dimethyl-2,2'-bipyridine-κN,N')copper(II).

Dong Xi-Yan XY Xu Xiaojie X Yang Lei L

Acta crystallographica. Section E, Structure reports online 20091003 Pt 11

In the crystal structure of the title compound, [Cu(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(H(2)O)], the Cu(II) ion is penta-coordinated in a distorted square-pyramidal geometry by two O atoms of two benzoate anions and two N atoms of a 5,5'-dimethyl-2,2'-bipyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O-H⋯O hydrogen bonds link the mol-ecules into a supra-molecular structure. The crystal studied was a racemic twin, as suggested by th ...[more]

PMID: 21578058

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