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[(Z)-O-Ethyl N-(4-nitro-phen-yl)thio-carbamato-?S](triphenyl-phosphine-?P)gold(I) dichloro-methane solvate.

ABSTRACT: An S,P-donor set in the title solvate, [Au(C(9)H(9)N(2)O(3)S)(C(18)H(15)P)]·CH(2)Cl(2), defines a linear geometry for the Au(I) atom [S-Au-P = 177.75?(7)°], with the minor distortion ascribed to the influence of an intra-molecular Au?O contact [3.019?(6)?Å]. In the crystal, the packing is stabilized by a network of C-H?S, C-H?N and C-H?O contacts.

SUBMITTER: Ho SY

PROVIDER: S-EPMC2971450 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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[(Z)-O-Ethyl N-(4-nitro-phen-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I) dichloro-methane solvate.

Ho Soo Yei SY Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

An S,P-donor set in the title solvate, [Au(C(9)H(9)N(2)O(3)S)(C(18)H(15)P)]·CH(2)Cl(2), defines a linear geometry for the Au(I) atom [S-Au-P = 177.75 (7)°], with the minor distortion ascribed to the influence of an intra-molecular Au⋯O contact [3.019 (6) Å]. In the crystal, the packing is stabilized by a network of C-H⋯S, C-H⋯N and C-H⋯O contacts. ...[more]

PMID: 21578192

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