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4-Bromo-2-{(E)-3-[1-(hydroxy-imino)eth-yl]phenyl-imino-meth-yl}phenol.

ABSTRACT: In the title compound, C(15)H(13)BrN(2)O(2), he oxime unit adopts an E conformation with respect to the O-H group. A classical intra-molecular O-H?N hydrogen bond results in the formation of a six-membered ring. The crystal structure is stabilized by inter-molecular O-H?N hydrogen bonds between the hydr-oxy groups and the oxime N atoms. In addition, the crystal structure also features short inter-molecular Br?Br short contacts with a distance of 3.8768?(5)?Å.

SUBMITTER: Xu L

PROVIDER: S-EPMC2971802 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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4-Bromo-2-{(E)-3-[1-(hydroxy-imino)eth-yl]phenyl-imino-meth-yl}phenol.

Xu Li L Wu Lei L

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

In the title compound, C(15)H(13)BrN(2)O(2), he oxime unit adopts an E conformation with respect to the O-H group. A classical intra-molecular O-H⋯N hydrogen bond results in the formation of a six-membered ring. The crystal structure is stabilized by inter-molecular O-H⋯N hydrogen bonds between the hydr-oxy groups and the oxime N atoms. In addition, the crystal structure also features short inter-molecular Br⋯Br short contacts with a distance of 3.8768 (5) Å. ...[more]

PMID: 21578872

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