Unknown

Dataset Information

0

Trans-Dichloridobis[tris-(4-methoxy-phen-yl)phosphine]palladium(II) benzene monosolvate.

ABSTRACT: The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)]·C(6)H(6), shows a square-planar geometry for the Pd(II) atom within a Cl(2)[P(PhOMe)(3)](2) ligand set. The crystal structure contains benzene as solvent. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom, one tris-(4-methoxy-phen-yl)phosphine ligand and one half of the benzene solvent mol-ecule.

SUBMITTER: van Blerk C 

PROVIDER: S-EPMC2971806 | biostudies-other | 2009

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

trans-Dichloridobis[tris-(4-methoxy-phen-yl)phosphine]palladium(II) benzene monosolvate.

van Blerk Charmaine C   Holzapfel Cedric W CW  

Acta crystallographica. Section E, Structure reports online 20091107 Pt 12

The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)]·C(6)H(6), shows a square-planar geometry for the Pd(II) atom within a Cl(2)[P(PhOMe)(3)](2) ligand set. The crystal structure contains benzene as solvent. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom, one tris-(4-methoxy-phen-yl)phosphine ligand and one half of the benzene solvent mol-ecule. ...[more]

Similar Datasets

Unknown trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II).
| S-EPMC2971166 | biostudies-literature
Unknown trans-Dibromidobis[tris-(4-chloro-phen-yl)phosphine]palladium(II).
| S-EPMC2971912 | biostudies-literature
Unknown Tris(2-methoxy-phen-yl)phosphine.
| S-EPMC2969262 | biostudies-literature
Unknown trans-Dichloridobis{tris-[4-(trifluoro-methyl)phen-yl]phosphane-?P}palla-dium(II) dichloro-methane monosolvate.
| S-EPMC3588757 | biostudies-literature
Unknown trans-Dichloridobis(triphenyl-phosphine)palladium(II).
| S-EPMC2961313 | biostudies-literature
Unknown trans-Dichloridobis(triisopropyl-phosphine-?P)palladium(II).
| S-EPMC2961642 | biostudies-literature
Unknown Dichlorido(η-toluene)[tris-(4-methoxy-phen-yl)phosphine]ruthenium(II).
| S-EPMC2960359 | biostudies-literature
Unknown trans-Dichloridobis[diphen-yl(thio-phen-2-yl)phosphane-?P]palladium(II).
| S-EPMC3344332 | biostudies-literature
Unknown trans-Dichloridobis[diphen-yl(4-vinyl-phen-yl)phosphane-?P]palladium(II).
| S-EPMC3238597 | biostudies-literature
Unknown cis-Dichloridobis[tris-(4-chloro-phen-yl)phosphane-?P]platinum(II) acetonitrile monosolvate.
| S-EPMC3435633 | biostudies-literature