Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[(Z)-N-(3-Chloro-phen-yl)-O-ethyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

ABSTRACT: The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S,P-donor set [S-Au-P = 175.86?(3)°]. The deviation from linearity is ascribed to the proximate O atom derived from the thio-carbamato anion [Au?O = 2.967?(3)?Å].

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2971815 | biostudies-other | 2009

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

[(Z)-N-(3-Chloro-phen-yl)-O-ethyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091125 Pt 12

The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S,P-donor set [S-Au-P = 175.86 (3)°]. The deviation from linearity is ascribed to the proximate O atom derived from the thio-carbamato anion [Au⋯O = 2.967 (3) Å]. ...[more]

PMID: 21578673

Similar Datasets

[(Z)-N-(2-Chloro-phen-yl)-O-ethyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], features a linear S,P-donor set with a small deviation from the ideal linear geometry due to the proximity of the meth-oxy O atom to Au [Au⋯O = 2.986 (4) Å].

| S-EPMC2971960 | biostudies-literature

[(Z)-O-Ethyl N-(4-chloro-phen-yl)thio-carbamato-?S](triphenyl-phosphine-?P)gold(I) dichloro-methane hemisolvate.

Project description:The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01?(4)°]; a close intra-molecular Au?O contact [2.964?(4)?Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H?N, C-H?S and C-H?? inter-actions. The solvent mol-ecule is disordered about a twofold rotation axis.

| S-EPMC2979641 | biostudies-literature

[(Z)-N-(4-Chloro-phen-yl)-O-methyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S-Au-P = 175.14?(5)°] due to the close approach of the O atom to the Au atom [Au?O = 2.882?(3)?Å]. Loosely associated dimers are formed in the crystal structure through C-H?O inter-actions.

| S-EPMC2972176 | biostudies-literature

[O-Ethyl (Z)-N-(2-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62?(5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra-molecular contact of 2.970?(5)?Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth-oxy group.

| S-EPMC2979177 | biostudies-literature

[(Z)-O-Ethyl-N-(p-tol-yl)thio-carbamato-?S](triphenyl-phosphine)-?P]gold(I).

Project description:The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom. The thio-carbamate ligand is orientated to place the aryl ring in close proximity to Au [the closest Au?C distance is 3.238?(4)?Å], which results in a small deviation from the ideal linear P-Au-S geometry.

| S-EPMC2972054 | biostudies-literature

[(Z)-O-Ethyl-N-(o-tol-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear geometry for the Au atom defined by the S and P donor atoms. A small deviation from the ideal geometry is noted and is ascribed to an intra-molecular Au⋯O contact [2.936 (4) Å]. Inversion dimers are formed in the crystal structure mediated by C-H⋯π inter-actions between centrosymmetrically related o-tolyl residues [C⋯Cg = 3.532 (6) Å].

| S-EPMC2971922 | biostudies-literature

[(Z)-O-Ethyl-N-propyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(6)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom with a deviation from linearity [S-Au-P = 176.66?(5)°] due to an intra-molecular Au?O contact [2.991?(5)?Å]. Supra-molecular dimers are formed in the crystal structure mediated by C-H?N inter-actions.

| S-EPMC2971786 | biostudies-literature

[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

Project description:The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S,P-donor set [S-Au-P angle = 174.61?(4)°], with the distortion related to a short intra-molecular Au?O contact [2.988?(3)?Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis by C-H?? inter-actions.

| S-EPMC2979546 | biostudies-other

[(Z)-N-(2-Chloro-phen-yl)-O-methyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

Project description:In the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], the Au(I) atom has a near-linear geometry, defined by an S,P-donor set [S-Au-P = 175.09?(5)°]. The proximity of the meth-oxy O atom to Au may be responsible for the deviation from linearity [Au?O = 2.959?(4)?Å].

| S-EPMC2971876 | biostudies-other

[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10?(5) and 177.26?(5)° for the two mol-ecules], with the distortion due in part to the close intra-molecular approach of the O atom [Au?O contacts = 3.054?(4) and 3.013?(4)?Å, respectively, for the two mol-ecules].

| S-EPMC2983779 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data