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Poly[aqua-bis(?(4)-naphthalene-1,4-di-carboxyl-ato)(1,10-phenanthroline-5,6-dione)dimanganese(II)].

ABSTRACT: The three-dimensional coordination polymer, [Mn(2)(C(12)H(6)O(4))(2)(C(12)H(6)N(2)O(2))(H(2)O)](n), features a water-coord-inated Mn(II) ion and an N-heterocycle-chelated Mn(II) ion, both in six-coordinate octa-hedral geometries. Of the two rigid dianions, one is bonded to four Mn(II) ions, with each of the O atoms being connected to a different metal ion. The other dianion uses one carboxyl-ate group to chelate to one Mn(II) ion and its other carboxyl-ate group to bind to two Mn(II) ions.

SUBMITTER: Cong FD

PROVIDER: S-EPMC2971822 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Poly[aqua-bis(μ(4)-naphthalene-1,4-di-carboxyl-ato)(1,10-phenanthroline-5,6-dione)dimanganese(II)].

Cong Fang-Di FD Yu Feng-Yang FY Wei Zhen Z Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20091107 Pt 12

The three-dimensional coordination polymer, [Mn(2)(C(12)H(6)O(4))(2)(C(12)H(6)N(2)O(2))(H(2)O)](n), features a water-coord-inated Mn(II) ion and an N-heterocycle-chelated Mn(II) ion, both in six-coordinate octa-hedral geometries. Of the two rigid dianions, one is bonded to four Mn(II) ions, with each of the O atoms being connected to a different metal ion. The other dianion uses one carboxyl-ate group to chelate to one Mn(II) ion and its other carboxyl-ate group to bind to two Mn(II) ions. ...[more]

PMID: 21578583

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