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Chlorido(1-cyclo-pentyl-idene-4-ethyl-thio-semicarbazidato-?N,S)diphenyl-tin(IV).

ABSTRACT: The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is penta-coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo-pentyl-idene-4-ethyl-thio-semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo-pentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, inter-molecular N-H?Cl hydrogen bonds form chains along [101].

SUBMITTER: Venkatraman R

PROVIDER: S-EPMC2971835 | biostudies-other | 2009 Nov

REPOSITORIES: biostudies-other

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Chlorido(1-cyclo-pentyl-idene-4-ethyl-thio-semicarbazidato-κN,S)diphenyl-tin(IV).

Venkatraman Ramaiyer R Sitole Lungile L Fronczek Frank R FR

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is penta-coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo-pentyl-idene-4-ethyl-thio-semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo-pentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, inter-molecular N-H⋯Cl hydrogen bonds form chains along [101] ...[more]

PMID: 21578665

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