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(3-Allyl-oxypicolinato-?N,O)bis-[3,5-difluoro-2-(2-pyrid-yl)phenyl-?C,N]iridium(III).

ABSTRACT: The title complex, [Ir(C(11)H(6)F(2)N)(2)(C(9)H(8)NO(3))], consists of one Ir(III) ion, two C,N-bidentate 3,5-difluoro-2-(2-pyrid-yl)phenyl (F(2)ppy) ligands and one N,O-bidentate 3-allyl-oxypicolinate (pic-3-Oall) ligand. The Ir(III) ion is hexa-coordinated by two C atoms and two N atoms from the F(2)ppy ligands and one N atom and one carboxyl-ate O atom from the pic-3-Oall ligand, displaying a distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H?F and C-H?O hydrogen bonds link the complex mol-ecules into a three-dimensional supra-molecular structure.

SUBMITTER: Zhao YL 

PROVIDER: S-EPMC2971841 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(3-Allyl-oxypicolinato-κN,O)bis-[3,5-difluoro-2-(2-pyrid-yl)phenyl-κC,N]iridium(III).

Zhao Yu-Ling YL   Meng Jing J  

Acta crystallographica. Section E, Structure reports online 20091111 Pt 12

The title complex, [Ir(C(11)H(6)F(2)N)(2)(C(9)H(8)NO(3))], consists of one Ir(III) ion, two C,N-bidentate 3,5-difluoro-2-(2-pyrid-yl)phenyl (F(2)ppy) ligands and one N,O-bidentate 3-allyl-oxypicolinate (pic-3-Oall) ligand. The Ir(III) ion is hexa-coordinated by two C atoms and two N atoms from the F(2)ppy ligands and one N atom and one carboxyl-ate O atom from the pic-3-Oall ligand, displaying a distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H⋯F and C-H⋯O hydrog  ...[more]

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