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{?(2)-1,4-Bis[2-(4-pyrid-yl)ethen-yl]benzene-?N:N'}bis-[bis-(acetyl-acetonato-?O,O')copper(II)].

ABSTRACT: The asymmetric unit of the title compound, [Cu(2)(C(5)H(7)O(2))(4)(C(20)H(16)N(2))], contains half of a centrosymmetric dinuclear mol-ecule. In the mol-ecule, each Cu center is coordinated by four O atoms from two acetyl-acetonate ligands and one N atom from the bridging linear 1,4-bis-[2-(4-pyrid-yl)ethen-yl]benzene ligand in a square-pyramidal geometry. In the crystal structure, weak inter-molecular C-H?O hydrogen bonds link mol-ecules into sheets parallel to the bc plane.

SUBMITTER: Jian FF

PROVIDER: S-EPMC2971849 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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{μ(2)-1,4-Bis[2-(4-pyrid-yl)ethen-yl]benzene-κN:N'}bis-[bis-(acetyl-acetonato-κO,O')copper(II)].

Jian Fang-Fang FF Wang Jing J Zhang Jing J

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

The asymmetric unit of the title compound, [Cu(2)(C(5)H(7)O(2))(4)(C(20)H(16)N(2))], contains half of a centrosymmetric dinuclear mol-ecule. In the mol-ecule, each Cu center is coordinated by four O atoms from two acetyl-acetonate ligands and one N atom from the bridging linear 1,4-bis-[2-(4-pyrid-yl)ethen-yl]benzene ligand in a square-pyramidal geometry. In the crystal structure, weak inter-molecular C-H⋯O hydrogen bonds link mol-ecules into sheets parallel to the bc plane. ...[more]

PMID: 21578648

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