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Bis(2-ethoxy-carbonyl-ethyl-?C,O)(2-thioxo-1,3-dithiole-4,5-dithiol-ato-?S,S)tin(IV).

ABSTRACT: In the title compound, [Sn(C(5)H(9)O(2))(2)(C(3)S(5))], the immediate environment around the Sn centre is defined by two S and two C atoms that define an approximately tetra-hedral geometry. The close approach of the pendant carbonyl O atoms [Sn-O = 2.577?(3) and 2.573?(3)?Å] increases the coordination number to six. Supra-molecular chains are formed along the a axis in the crystal structure owing to the presence of C-H?O contacts.

SUBMITTER: de Lima GM

PROVIDER: S-EPMC2971863 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis(2-ethoxy-carbonyl-ethyl-κC,O)(2-thioxo-1,3-dithiole-4,5-dithiol-ato-κS,S)tin(IV).

de Lima Geraldo M GM Wardell Solange M S V SM Wardell James L JL Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

In the title compound, [Sn(C(5)H(9)O(2))(2)(C(3)S(5))], the immediate environment around the Sn centre is defined by two S and two C atoms that define an approximately tetra-hedral geometry. The close approach of the pendant carbonyl O atoms [Sn-O = 2.577 (3) and 2.573 (3) Å] increases the coordination number to six. Supra-molecular chains are formed along the a axis in the crystal structure owing to the presence of C-H⋯O contacts. ...[more]

PMID: 21578652

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