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[N'-(5-Chloro-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]diphenyl-tin(IV).

ABSTRACT: The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C-Sn-C = 125.7?(2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2?(3)°. Intra-molecular O-H?N hydrogen bonding is present in the crystal structure.

SUBMITTER: Lee SM

PROVIDER: S-EPMC2971880 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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[N'-(5-Chloro-2-oxidobenzyl-idene-κO)-3-hydr-oxy-2-naphthohydrazidato-κN',O]diphenyl-tin(IV).

Lee See Mun SM Lo Kong Mun KM Ali Hapipah Mohd HM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20091128 Pt 12

The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)°. Intra-molecular O-H⋯N hydrogen bonding is present in the crystal structure. ...[more]

PMID: 21578694

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