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(2,2'-Bipyrid-yl)bis-[N,N-bis-(2-hydroxy-ethyl)dithio-carbamato-?S,S']cadmium(II).

ABSTRACT: The title compound, [Cd(C(5)H(10)NO(2)S(2))(2)(C(10)H(8)N(2))], features a trigonal-prismatic coordination geometry for the Cd(II) ion, based on an N(2)S(4) donor set defined by two chelating dithio-carbamate ligands and a 2,2'-bipyridyl ligand. In the crystal, extensive O-H?O hydrogen bonding results in the formation of 12-membered {?HO}(6) synthons and one-dimensional supra-molecular chains with further O-H?S inter-actions providing additional stability to the linear chain with base vector [01].

SUBMITTER: Song JC

PROVIDER: S-EPMC2971885 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(2,2'-Bipyrid-yl)bis-[N,N-bis-(2-hydroxy-ethyl)dithio-carbamato-κS,S']cadmium(II).

Song Juyoung C JC Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091125 Pt 12

The title compound, [Cd(C(5)H(10)NO(2)S(2))(2)(C(10)H(8)N(2))], features a trigonal-prismatic coordination geometry for the Cd(II) ion, based on an N(2)S(4) donor set defined by two chelating dithio-carbamate ligands and a 2,2'-bipyridyl ligand. In the crystal, extensive O-H⋯O hydrogen bonding results in the formation of 12-membered {⋯HO}(6) synthons and one-dimensional supra-molecular chains with further O-H⋯S inter-actions providing additional stability to the linear chain with base vector [01 ...[more]

PMID: 21578677

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