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Bis(2-amino-thia-zole-4-acetato)aquazinc(II).


ABSTRACT: In the title compound, [Zn(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the central Zn atom (2 site symmetry) is five-coordinated by two N and three O atoms [Zn-N = 2.047?(3)?Å, Zn-O = 2.099?(2) and 1.974?(4)?Å] in a distorted square-pyramidal geometry. Besides one O atom from a water mol-ecule, two 2-amino-thia-zole-4-acetate ligands provide two N and two O atoms as coordinated atoms. In the crystal structure, inter-molecular O-H?O and N-H?O hydrogen bonds connect the mol-ecules into an infinite three-dimensional framework.

SUBMITTER: Zhang LJ 

PROVIDER: S-EPMC2971890 | biostudies-other | 2009 Nov

REPOSITORIES: biostudies-other

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Bis(2-amino-thia-zole-4-acetato)aquazinc(II).

Zhang Lai-Jun LJ   Shen Xing-Can XC   Yang Yan Y   Liang Hong H  

Acta crystallographica. Section E, Structure reports online 20091104 Pt 12


In the title compound, [Zn(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the central Zn atom (2 site symmetry) is five-coordinated by two N and three O atoms [Zn-N = 2.047 (3) Å, Zn-O = 2.099 (2) and 1.974 (4) Å] in a distorted square-pyramidal geometry. Besides one O atom from a water mol-ecule, two 2-amino-thia-zole-4-acetate ligands provide two N and two O atoms as coordinated atoms. In the crystal structure, inter-molecular O-H⋯O and N-H⋯O hydrogen bonds connect the mol-ecules into an infinite three-dimens  ...[more]

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