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Bis[?-1,2-diphenyl-N,N'-bis-(di-2-pyridyl-methyl-eneamino)ethane-1,2-diimine]disilver(I) bis-(hexa-fluorido-phosphate) acetonitrile disolvate.

ABSTRACT: In the centrosymmetric dinuclear title compound, [Ag(2)(C(36)H(26)N(8))(2)](PF(6))(2)·2C(2)H(3)N, the Ag(+) ion is bound to four N atoms from two 1,2-diphenyl-N,N'-bis-(di-2-pyridyl-methyl-eneamino)ethane-1,2-diimine ligands in a distorted tetra-hedral geometry. The ligand adopts a twist conformation, coordinating two metal centers by three pyridyl N atoms and one imine N atom and spanning two Ag(+) ions, resulting in the formation of a helical dimeric structure.

SUBMITTER: Sun Q

PROVIDER: S-EPMC2971906 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis[μ-1,2-diphenyl-N,N'-bis-(di-2-pyridyl-methyl-eneamino)ethane-1,2-diimine]disilver(I) bis-(hexa-fluorido-phosphate) acetonitrile disolvate.

Sun Qiaozhen Q Xiao Tao T Chen Ping P Gan Xiaoqiang X Bao Lin L

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

In the centrosymmetric dinuclear title compound, [Ag(2)(C(36)H(26)N(8))(2)](PF(6))(2)·2C(2)H(3)N, the Ag(+) ion is bound to four N atoms from two 1,2-diphenyl-N,N'-bis-(di-2-pyridyl-methyl-eneamino)ethane-1,2-diimine ligands in a distorted tetra-hedral geometry. The ligand adopts a twist conformation, coordinating two metal centers by three pyridyl N atoms and one imine N atom and spanning two Ag(+) ions, resulting in the formation of a helical dimeric structure. ...[more]

PMID: 21578653

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