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{2,2'-[5-Bromo-pyridine-2,3-diylbis(nitrilo-methyl-idyne)]diphenolato}chlorido(dimethyl-formamide)manganese(III).

ABSTRACT: In the title complex, [Mn(C(19)H(12)BrN(3)O(2))Cl(C(3)H(7)NO)], the Mn(III) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, one O atom from the dimethyl-formamide ligand and a Cl anion in a distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H?Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers with a short distance of 3.878?(3)?Å between the centroids of the aromatic rings.

SUBMITTER: Xie H 

PROVIDER: S-EPMC2972037 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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{2,2'-[5-Bromo-pyridine-2,3-diylbis(nitrilo-methyl-idyne)]diphenolato}chlorido(dimethyl-formamide)manganese(III).

Xie Hai H   Meng Shuangming S   Zhu Yongjun Y   Bai Peiwan P  

Acta crystallographica. Section E, Structure reports online 20091125 Pt 12

In the title complex, [Mn(C(19)H(12)BrN(3)O(2))Cl(C(3)H(7)NO)], the Mn(III) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, one O atom from the dimethyl-formamide ligand and a Cl anion in a distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers with a short distance of 3.878 (3) Å between the centroids of the aromatic rings. ...[more]