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Di-?(2)-bromido-bis-[bromido(?-1,2,4,5-tetra-methyl-benzene)ruthenium(II)].

ABSTRACT: The asymmetric unit of the title compound, [Ru(2)Br(4)(C(10)H(14))(2)], contains one half of the centrosymmetric mol-ecule. Each Ru center is coordinated by tetra-methyl-benzene ring in a ?(6)-coordination mode, and one terminal and two bridging bromine atoms. The aromatic rings and the Ru(2)Br(2) four-membered ring form a dihedral angle of 55.99?(8)°. In the crystal structure, weak inter-molecular C-H?Br inter-actions link mol-ecules into chains propagated in [001].

SUBMITTER: Espinosa-Jalapa N

PROVIDER: S-EPMC2972084 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Di-μ(2)-bromido-bis-[bromido(η-1,2,4,5-tetra-methyl-benzene)ruthenium(II)].

Espinosa-Jalapa Noel N Hernández-Ortega Simón S Le Lagadec Ronan R Morales-Morales David D

Acta crystallographica. Section E, Structure reports online 20091128 Pt 12

The asymmetric unit of the title compound, [Ru(2)Br(4)(C(10)H(14))(2)], contains one half of the centrosymmetric mol-ecule. Each Ru center is coordinated by tetra-methyl-benzene ring in a η(6)-coordination mode, and one terminal and two bridging bromine atoms. The aromatic rings and the Ru(2)Br(2) four-membered ring form a dihedral angle of 55.99 (8)°. In the crystal structure, weak inter-molecular C-H⋯Br inter-actions link mol-ecules into chains propagated in [001]. ...[more]

PMID: 21578690

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