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2,4-Dibromo-6-{(E)-[(R)-1-phenyl-ethyl]imino-meth-yl}phenol.

ABSTRACT: In the title Schiff base, C(15)H(13)Br(2)NO, the benzene and phenyl rings form a dihedral angle of 75.18?(13)°. The N=C bond length of 1.263?(6)?Å is shorter than of the N-C bond [1.476?(5)?Å], indicating a double bond. In the crystal, there is some pseudosymmetry. This occurs because most of the two mol-ecules are centrosymmetrically related. The mol-ecular structure is stabilized by intra-molecular O-H?N hydrogen bonds.

SUBMITTER: Xia DG

PROVIDER: S-EPMC2972087 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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2,4-Dibromo-6-{(E)-[(R)-1-phenyl-ethyl]imino-meth-yl}phenol.

Xia Dong-Guo DG Ye Ya-Fen YF Lei Ke-Wei KW

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

In the title Schiff base, C(15)H(13)Br(2)NO, the benzene and phenyl rings form a dihedral angle of 75.18 (13)°. The N=C bond length of 1.263 (6) Å is shorter than of the N-C bond [1.476 (5) Å], indicating a double bond. In the crystal, there is some pseudosymmetry. This occurs because most of the two mol-ecules are centrosymmetrically related. The mol-ecular structure is stabilized by intra-molecular O-H⋯N hydrogen bonds. ...[more]

PMID: 21578884

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