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Tetra-aqua-bis[3-(4-pyrid-yl)benzoato-?N]nickel(II).

ABSTRACT: The Ni(II) atom in the title compound, [Ni(C(12)H(8)NO(2))(2)(H(2)O)(4)], exists in an all-trans octa-hedral coordination environment. The 3-(4-pyrid-yl)benzoate ligand binds to Ni atom through the pyridyl N atom; the pyridine and benzene rings are oriented at a dihedral angle of 26.27?(10)°. Adjacent complexes are linked by O-H?O hydrogen bonds, forming a three-dimensional network. The metal atom lies on a special position of 2 site symmetry in the crystal structure.

SUBMITTER: Wang QX

PROVIDER: S-EPMC2972113 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Tetra-aqua-bis[3-(4-pyrid-yl)benzoato-κN]nickel(II).

Wang Qiang-Xin QX Zeng Ming-Hua MH Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20091128 Pt 12

The Ni(II) atom in the title compound, [Ni(C(12)H(8)NO(2))(2)(H(2)O)(4)], exists in an all-trans octa-hedral coordination environment. The 3-(4-pyrid-yl)benzoate ligand binds to Ni atom through the pyridyl N atom; the pyridine and benzene rings are oriented at a dihedral angle of 26.27 (10)°. Adjacent complexes are linked by O-H⋯O hydrogen bonds, forming a three-dimensional network. The metal atom lies on a special position of 2 site symmetry in the crystal structure. ...[more]

PMID: 21578709

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