Ontology highlight
ABSTRACT:
SUBMITTER: Venter JA
PROVIDER: S-EPMC2972147 | biostudies-other | 2009
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20091114 Pt 12
The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O'-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenyl-phosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O-Rh-O bite angle of 77.74 (10)°. There are no classical hyd ...[more]