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Carbon-yl(N-nitroso-N-oxido-1-naphtylamine-?O,O')(triphenyl-phosphine-?P)rhodium(I) acetone solvate.

ABSTRACT: The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O'-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenyl-phosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O-Rh-O bite angle of 77.74?(10)°. There are no classical hydrogen-bond inter-actions observed for this complex.

SUBMITTER: Venter JA

PROVIDER: S-EPMC2972147 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Carbon-yl(N-nitroso-N-oxido-1-naphtylamine-κO,O')(triphenyl-phosphine-κP)rhodium(I) acetone solvate.

Venter Johan A JA Purcell W W Visser H G HG Muller T J TJ

Acta crystallographica. Section E, Structure reports online 20091114 Pt 12

The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O'-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenyl-phosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O-Rh-O bite angle of 77.74 (10)°. There are no classical hyd ...[more]

PMID: 21578610

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