Unknown

Dataset Information

0

Tetra-?(2)-acetato-bis-{?(2)-5-meth-oxy-2-[(2-morpholinoeth-yl)iminio-meth-yl]phenolato}tricadmium(II).

ABSTRACT: The central Cd(II) atom in the trinuclear title compound, [Cd(3)(C(14)H(19)N(2)O(3))(2)(CH(3)COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octa-hedral geometry. Two of the acetate groups function in a ?(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a ?(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation.

SUBMITTER: Mohd Lair N 

PROVIDER: S-EPMC2977297 | biostudies-other | 2009

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Tetra-μ(2)-acetato-bis-{μ(2)-5-meth-oxy-2-[(2-morpholinoeth-yl)iminio-meth-yl]phenolato}tricadmium(II).

Mohd Lair Nooraziah N   Mohd Ali Hapipah H   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20090731 Pt 8

The central Cd(II) atom in the trinuclear title compound, [Cd(3)(C(14)H(19)N(2)O(3))(2)(CH(3)COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octa-hedral geometry. Two of the acetate groups function in a μ(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a κ(3)-bondin  ...[more]

Similar Datasets

Unknown Bis{?-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}bis-({2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}copper(II)).
| S-EPMC3790358 | biostudies-literature
Unknown Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)-meth-yl]-imino-meth-yl}phenolato)-copper(II) dihydrate.
| S-EPMC2968260 | biostudies-literature
Unknown Bis[2-(cyclo-pentyl-imino-meth-yl)-5-meth-oxy-phenolato]copper(II).
| S-EPMC3007536 | biostudies-literature
Unknown Bis{2-meth-oxy-6-[(3-pyrid-yl)methyl-imino-meth-yl]phenolato}copper(II).
| S-EPMC2970154 | biostudies-literature
Unknown Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato}palladium(II).
| S-EPMC3120330 | biostudies-literature
Unknown Bis(?-6-meth-oxy-2-{[(3-oxidoprop-yl)imino]-meth-yl}phenolato)nickel(II) methanol monosolvate.
| S-EPMC3772446 | biostudies-literature
Unknown Bis{5-meth-oxy-2-[(1H-pyrrol-2-yl)methyl-imino-meth-yl]phenolato}zinc(II).
| S-EPMC2970064 | biostudies-literature
Unknown Bis{2-[(2-furylmeth-yl)imino-meth-yl]-5-meth-oxy-phenolato-?N,O}zinc(II).
| S-EPMC3099774 | biostudies-literature
Unknown Bis{2-meth-oxy-6-[3-(methyl-amino)propyl-imino-meth-yl]phenolato}nickel(II) bis-(perchlorate).
| S-EPMC2961174 | biostudies-literature
Unknown Bis{2-[imino-(phen-yl)meth-yl]-5-meth-oxy-phenolato-?(2)N,O(1)}nickel(II).
| S-EPMC3515134 | biostudies-literature