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Tetra-kis(2-amino-6-methyl-pyridinium) hexa-chloridobismuthate(III) chloride monohydrate.

ABSTRACT: The asymmetric unit of the title compound, (C(6)H(9)N(2))(4)[BiCl(6)]Cl·H(2)O, contains four protonated 2-amino-6-methyl-pyridine (HAMP) cations and two-halves of two [BiCl(6)](3-) anions, together with one water mol-ecule and one chloride anion. The Bi(III) atoms are hexa-coordinated by Cl atoms, forming distorted octa-hedral geometries. In the crystal structure, intra-molecular O-H?Cl and N-H?Cl, and inter-molecular O-H?Cl and N-H?O inter-actions link the mol-ecules into a three-dimensional network.

SUBMITTER: Yang Z 

PROVIDER: S-EPMC2977446 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Tetra-kis(2-amino-6-methyl-pyridinium) hexa-chloridobismuthate(III) chloride monohydrate.

Yang Zhen Z   Chen Gang G   Xu Wei W   Fan Zheng Z  

Acta crystallographica. Section E, Structure reports online 20090708 Pt 8

The asymmetric unit of the title compound, (C(6)H(9)N(2))(4)[BiCl(6)]Cl·H(2)O, contains four protonated 2-amino-6-methyl-pyridine (HAMP) cations and two-halves of two [BiCl(6)](3-) anions, together with one water mol-ecule and one chloride anion. The Bi(III) atoms are hexa-coordinated by Cl atoms, forming distorted octa-hedral geometries. In the crystal structure, intra-molecular O-H⋯Cl and N-H⋯Cl, and inter-molecular O-H⋯Cl and N-H⋯O inter-actions link the mol-ecules into a three-dimensional ne  ...[more]