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2-(Methoxy-carbon-yl)anilinium dihydrogen phosphate.

ABSTRACT: The title compound, C(8)H(10)NO(2) (+)·H(2)PO(4) (-), is a derivative of the naturally occurring compound methyl-anthranilate. The asymmetric unit comprises the 2-(methoxy-carbon-yl)anilinium cation and the dihydrogen phosphate anion. In the cation, the dihedral angle between the benzene ring plane and that through the methyl ester substituent is 22.94?(9)°. In the crystal, adjacent cations and anions form dimers through N-H?O and O-H?O hydrogen bonds, respectively. Additional N-H?O and C-H?O contacts result in a network of cation and anion dimers stacked down the b axis.

SUBMITTER: Shafiq M

PROVIDER: S-EPMC2977506 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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2-(Methoxy-carbon-yl)anilinium dihydrogen phosphate.

Shafiq Muhammad M Khan Islam Ullah IU Arshad Muhammad Nadeem MN Khan Muneeb Hayat MH Simpson Jim J

Acta crystallographica. Section E, Structure reports online 20090704 Pt 8

The title compound, C(8)H(10)NO(2) (+)·H(2)PO(4) (-), is a derivative of the naturally occurring compound methyl-anthranilate. The asymmetric unit comprises the 2-(methoxy-carbon-yl)anilinium cation and the dihydrogen phosphate anion. In the cation, the dihedral angle between the benzene ring plane and that through the methyl ester substituent is 22.94 (9)°. In the crystal, adjacent cations and anions form dimers through N-H⋯O and O-H⋯O hydrogen bonds, respectively. Additional N-H⋯O and C-H⋯O co ...[more]

PMID: 21583492

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