Unknown

Dataset Information

0

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin-1-ium tetra-chloridoaurate(III).


ABSTRACT: Both the cation and anion of the title compound, (C(26)H(21)N(2))[AuCl(4)], are disposed about a plane of mirror symmetry. The 2,9-dimethyl-4,7-diphenyl-1,10-phenanthrolinium ring is oriented at a dihedral angle of 44.2?(1)° with respect to the planar phenyl ring systems. The Au(III) atom has a square-planar environment defined by four Cl atoms. The crystal structure is stabilized by C-H?? and Au?? ring-metal (3.551?Å) inter-actions. In the crystal structure, the mol-ecules stack along the c axis via N-H?N hydrogen-bond inter-actions.

SUBMITTER: Y?ld?r?m SO 

PROVIDER: S-EPMC2977548 | biostudies-other | 2009

REPOSITORIES: biostudies-other

altmetric image

Publications

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin-1-ium tetra-chloridoaurate(III).

Yıldırım Sema Öztürk SÖ   Akkurt Mehmet M   Safari Nasser N   Abedi Anita A   Amani Vahid V   McKee Vickie V   McKee Vickie V  

Acta crystallographica. Section E, Structure reports online 20090402 Pt 5


Both the cation and anion of the title compound, (C(26)H(21)N(2))[AuCl(4)], are disposed about a plane of mirror symmetry. The 2,9-dimethyl-4,7-diphenyl-1,10-phenanthrolinium ring is oriented at a dihedral angle of 44.2 (1)° with respect to the planar phenyl ring systems. The Au(III) atom has a square-planar environment defined by four Cl atoms. The crystal structure is stabilized by C-H⋯π and Au⋯π ring-metal (3.551 Å) inter-actions. In the crystal structure, the mol-ecules stack along the c axi  ...[more]

Similar Datasets

| S-EPMC3393176 | biostudies-other
| S-EPMC3885051 | biostudies-literature
| S-EPMC3050301 | biostudies-literature
| S-EPMC2977193 | biostudies-literature
| S-EPMC2960497 | biostudies-literature
| S-EPMC2980224 | biostudies-literature
| S-EPMC3588511 | biostudies-literature
| S-EPMC3998259 | biostudies-literature
| S-EPMC3884443 | biostudies-other
| S-EPMC2969232 | biostudies-other