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[2,6-Bis(di-tert-butyl-phosphinometh-yl)phenyl-?P,C,P'](trifluoro-acetato)palladium(II).

ABSTRACT: The Pd(II) atom in the title compound, [Pd(C(2)F(3)O(2))(C(24)H(43)P(2))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intra-molecular C-H?O hydrogen bonds occur. The crystal packing reveals one weak inter-molecular C-H?O hydrogen bond, which self-assembles the mol-ecules into infinite chains parallel to the b axis.

SUBMITTER: Johnson MT

PROVIDER: S-EPMC2979456 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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[2,6-Bis(di-tert-butyl-phosphinometh-yl)phenyl-κP,C,P'](trifluoro-acetato)palladium(II).

Johnson Magnus T MT Cetina Mario M Rissanen Kari K Wendt Ola F OF

Acta crystallographica. Section E, Structure reports online 20100519 Pt 6

The Pd(II) atom in the title compound, [Pd(C(2)F(3)O(2))(C(24)H(43)P(2))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intra-molecular C-H⋯O hydrogen bonds occur. The crystal packing reveals one weak inter-molecular C-H⋯O hydrogen bond, which self-assembles the mol-ecules into infinite chains parallel to the b axis. ...[more]

PMID: 21579315

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