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Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-?N,O)bis-(nitrato-?O,O')cadmium(II).

ABSTRACT: In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl-pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra-molecular N-H?O hydrogen bonds occur. The crystal packing is stabilized by inter-molecular N-H?O and C-H?O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups.

SUBMITTER: Kaabi K

PROVIDER: S-EPMC2979534 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II).

Kaabi Kamel K El Glaoui Meher M Pereira Silva P S PS Ramos Silva M M Ben Nasr Cherif C

Acta crystallographica. Section E, Structure reports online 20100508 Pt 6

In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl-pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing is stabilized by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups. ...[more]

PMID: 21579276

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