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Poly[bis-(N,N-dimethyl-formamide-?O)(?(4)-naphthalene-1,5-disulfonato)magnesium(II)].

ABSTRACT: The structure of the title compound, [Mg(C(10)H(6)O(6)S(2))(C(3)H(7)NO)(2)](n), consists of MgO(6) octa-hedra ( symmetry) connected to naphthalene-1,5-disulfonate ligands ( symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethyl-formamide (DMF) mol-ecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg(2+) atom. Disorder over two positions was found in the DMF mol-ecule in a 0.518?(8):0.482?(8) ratio.

SUBMITTER: Borkowski LA

PROVIDER: S-EPMC2979591 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Poly[bis-(N,N-dimethyl-formamide-κO)(μ(4)-naphthalene-1,5-disulfonato)magnesium(II)].

Borkowski Lauren A LA Banerjee Debasis D Parise John B JB

Acta crystallographica. Section E, Structure reports online 20100522 Pt 6

The structure of the title compound, [Mg(C(10)H(6)O(6)S(2))(C(3)H(7)NO)(2)](n), consists of MgO(6) octa-hedra ( symmetry) connected to naphthalene-1,5-disulfonate ligands ( symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethyl-formamide (DMF) mol-ecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is boun ...[more]

PMID: 21579330

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