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(2,2'-Bipyridine-?N,N')bis-(4-hydroxy-benzoato-?O,O')lead(II) monohydrate.

ABSTRACT: The reaction of lead acetate, 4-hydroxy-benzoic acid and 2,2'-bipyridine in aqueous solution gave the title complex, [Pb(C(7)H(5)O(3))(2)(C(10)H(8)N(2))]·H(2)O. The asymmetric unit contains one Pb(II) atom, two 4-hydroxy-benzoate ligands, one 2,2'-bipyridine ligand and one uncoordinated water mol-ecule. The Pb(II) atom is hexa-coordinated in a distorted tetra-gonal-bipyramidal geometry and is chelated by four carboxyl-ate O atoms and two N atoms. O-H?O hydrogen-bonding inter-actions, involving the uncoordinated water, the carboxyl-ate O atoms and hydr-oxy O atoms, produce a three-dimensional supra-molecular structure.

SUBMITTER: Dai J

PROVIDER: S-EPMC2979701 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(2,2'-Bipyridine-κN,N')bis-(4-hydroxy-benzoato-κO,O')lead(II) monohydrate.

Dai Jun J Yang Juan J

Acta crystallographica. Section E, Structure reports online 20100130 Pt 2

The reaction of lead acetate, 4-hydroxy-benzoic acid and 2,2'-bipyridine in aqueous solution gave the title complex, [Pb(C(7)H(5)O(3))(2)(C(10)H(8)N(2))]·H(2)O. The asymmetric unit contains one Pb(II) atom, two 4-hydroxy-benzoate ligands, one 2,2'-bipyridine ligand and one uncoordinated water mol-ecule. The Pb(II) atom is hexa-coordinated in a distorted tetra-gonal-bipyramidal geometry and is chelated by four carboxyl-ate O atoms and two N atoms. O-H⋯O hydrogen-bonding inter-actions, involving t ...[more]

PMID: 21579690

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Aqua-(2,2'-bipyridine)bis-(4-hydroxy-benzoato)zinc(II).

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(2,2'-Bipyridine-?N,N')bis-(4-methyl-benzoato-?O,O')zinc(II).

Project description:In the title compound, [Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by four O atoms from two chelating 4-methyl-benzoate ligands and two N atoms from a 2,2'-bipyridine ligand, displaying a disordered octahedral geometry. C-H?O hydrogen bonds connect the complex mol-ecules into a three-dimensional supra-molecular structure.

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