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Tert-Butyl 2-(4-chloro-benzo-yl)-2-methyl-propanoate.

ABSTRACT: The title compound, C(15)H(19)ClO(3), is bent with a dihedral angle of 72.02?(9)° between the mean planes of the benzene ring and a group encompassing the ester functionality (O=C-O-C). In the crystal, mol-ecules related by inversion symmetry are connected by weak C-H?O inter-actions into infinite chains. These inter-actions involve H atoms from a methyl group of the dimethyl residue and the O atoms of the ketone on one side of a mol-ecule; on the other side there are inter-actions between H atoms of the benzene ring and the carbonyl O atoms of the ester functionality. There are no directional inter-actions between the chains.

SUBMITTER: Crosse CM

PROVIDER: S-EPMC2979824 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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tert-Butyl 2-(4-chloro-benzo-yl)-2-methyl-propanoate.

Crosse Chelsey M CM Kelly Emily C EC Logue Marshall W MW Luck Rudy L RL Maass John S JS Mehne Katlyn C KC Pignotti Louis R LR

Acta crystallographica. Section E, Structure reports online 20100130 Pt 2

The title compound, C(15)H(19)ClO(3), is bent with a dihedral angle of 72.02 (9)° between the mean planes of the benzene ring and a group encompassing the ester functionality (O=C-O-C). In the crystal, mol-ecules related by inversion symmetry are connected by weak C-H⋯O inter-actions into infinite chains. These inter-actions involve H atoms from a methyl group of the dimethyl residue and the O atoms of the ketone on one side of a mol-ecule; on the other side there are inter-actions between H ato ...[more]

PMID: 21579898

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tert-Butyl 2-methyl-2-(4-methyl-benzo-yl)propanoate.

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