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Diacridinium tetra-kis(thio-cyanato-?S)platinate(II).

ABSTRACT: The asymmetric unit of the title compound, (C(13)H(10)N)(2)[Pt(NCS)(4)], contains a protonated acridine molecule and one half of a [Pt(NCS)(4)](2-) anion. In the complex anion, the Pt(II) ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment by four S atoms from four thio-cyanate ligands. The compound displays numerous inter-molecular ?-? inter-actions between six-membered rings, with a shortest centroid-centroid distance of 3.682?(3)?Å. The component ions inter-act by means of inter-molecular N-H?N hydrogen bonds.

SUBMITTER: Ha K

PROVIDER: S-EPMC2979885 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Diacridinium tetra-kis(thio-cyanato-κS)platinate(II).

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20100123 Pt 2

The asymmetric unit of the title compound, (C(13)H(10)N)(2)[Pt(NCS)(4)], contains a protonated acridine molecule and one half of a [Pt(NCS)(4)](2-) anion. In the complex anion, the Pt(II) ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment by four S atoms from four thio-cyanate ligands. The compound displays numerous inter-molecular π-π inter-actions between six-membered rings, with a shortest centroid-centroid distance of 3.682 (3) Å. ...[more]

PMID: 21579664

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