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Bis[tris-(ethane-1,2-diamine)nickel(II)] octa-cyanidomolybdate(IV) penta-hydrate.

ABSTRACT: In the title compound, [Ni(C(2)H(8)N(2))(3)](2)[Mo(CN)(8)]·5H(2)O, the Ni(II) ion is coordinated by six N atoms from three ethane-1,2-diamine ligands in a distorted octa-hedral geometry, while the Mo(IV) atom is coordianted by eight cyanide ligands. The Ni-N bond distances range from 2.1061?(18) to 2.1425?(18)?Å. The Mo-C and C-N distances in the [Mo(CN)(8)] unit range from 2.154?(2) to 2.174?(2)?Å and 1.149?(3) to 1.156?(3)?Å, respectively. The complex ions and water mol-ecules are linked by weak N-H?N/O and O-H?N/O hydrogen bonds into a three-demensional structure.

SUBMITTER: Jun Q

PROVIDER: S-EPMC2980088 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis[tris-(ethane-1,2-diamine)nickel(II)] octa-cyanidomolybdate(IV) penta-hydrate.

Jun Qian Q Zhang Chi C

Acta crystallographica. Section E, Structure reports online 20091209 Pt 1

In the title compound, [Ni(C(2)H(8)N(2))(3)](2)[Mo(CN)(8)]·5H(2)O, the Ni(II) ion is coordinated by six N atoms from three ethane-1,2-diamine ligands in a distorted octa-hedral geometry, while the Mo(IV) atom is coordianted by eight cyanide ligands. The Ni-N bond distances range from 2.1061 (18) to 2.1425 (18) Å. The Mo-C and C-N distances in the [Mo(CN)(8)] unit range from 2.154 (2) to 2.174 (2) Å and 1.149 (3) to 1.156 (3) Å, respectively. The complex ions and water mol-ecules are linked by we ...[more]

PMID: 21579925

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