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Aqua-[4-chloro-2-(2-pyridylmethyl-imino-meth-yl)phenolato]copper(II) nitrate monohydrate.

ABSTRACT: In the title mononuclear complex, [Cu(C(13)H(10)ClN(2)O)(H(2)O)]-NO(3)·H(2)O, the Cu(II) atom is four-coordinated by two N atoms and one O atom of the tridentate Schiff base ligand and one O atom from the coordinated water mol-ecule in a slightly distorted square-planar configuration. The nitrate ion inter-acts with the copper center [Cu1?O3 = 2.579?(4)?Å]. In the crystal, the cations, anions and water mol-ecules are linked by O-H?O and O-H?N hydrogen bonds.

SUBMITTER: Liang Q

PROVIDER: S-EPMC2980213 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Aqua-[4-chloro-2-(2-pyridylmethyl-imino-meth-yl)phenolato]copper(II) nitrate monohydrate.

Liang Qing Q Chen Xiaodan X Zhang Huaihong H Zou Zhihong Z

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the title mononuclear complex, [Cu(C(13)H(10)ClN(2)O)(H(2)O)]-NO(3)·H(2)O, the Cu(II) atom is four-coordinated by two N atoms and one O atom of the tridentate Schiff base ligand and one O atom from the coordinated water mol-ecule in a slightly distorted square-planar configuration. The nitrate ion inter-acts with the copper center [Cu1⋯O3 = 2.579 (4) Å]. In the crystal, the cations, anions and water mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds. ...[more]

PMID: 21579939

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