Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Aqua-[4-chloro-2-(2-pyridylmethyl-imino-meth-yl)phenolato]copper(II) nitrate monohydrate.

ABSTRACT: In the title mononuclear complex, [Cu(C(13)H(10)ClN(2)O)(H(2)O)]-NO(3)·H(2)O, the Cu(II) atom is four-coordinated by two N atoms and one O atom of the tridentate Schiff base ligand and one O atom from the coordinated water mol-ecule in a slightly distorted square-planar configuration. The nitrate ion inter-acts with the copper center [Cu1?O3 = 2.579?(4)?Å]. In the crystal, the cations, anions and water mol-ecules are linked by O-H?O and O-H?N hydrogen bonds.

SUBMITTER: Liang Q

PROVIDER: S-EPMC2980213 | biostudies-other | 2009

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Aqua-[4-chloro-2-(2-pyridylmethyl-imino-meth-yl)phenolato]copper(II) nitrate monohydrate.

Liang Qing Q Chen Xiaodan X Zhang Huaihong H Zou Zhihong Z

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the title mononuclear complex, [Cu(C(13)H(10)ClN(2)O)(H(2)O)]-NO(3)·H(2)O, the Cu(II) atom is four-coordinated by two N atoms and one O atom of the tridentate Schiff base ligand and one O atom from the coordinated water mol-ecule in a slightly distorted square-planar configuration. The nitrate ion inter-acts with the copper center [Cu1⋯O3 = 2.579 (4) Å]. In the crystal, the cations, anions and water mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds. ...[more]

PMID: 21579939

Similar Datasets

Aqua-[2-(2-pyridylmethyl-imino-meth-yl)phenolato]nickel(II) nitrate monohydrate.

Project description:In the title compound, [Ni(C(13)H(11)N(2)O)(H(2)O)]NO(3)·H(2)O, the Ni(II) ion is coordinated by one O atom and two N atoms of the Schiff base ligand and the O atom from a water mol-ecule, forming a slightly distorted square-planar geometry. A one-dimensional double-chain structure is formed along [001] by O?H-O hydrogen bonds and the Ni?O [2.617?(3)?Å] inter-actions.

| S-EPMC2971029 | biostudies-literature

(Dicyanamido)[2-(2-pyridylmethyl-imino-meth-yl)phenolato]copper(II) monohydrate.

Project description:The title compound, [Cu(C(13)H(11)N(2)O)(C(2)N(3))]·H(2)O, is a mononuclear copper(II) complex in which the Cu(II) ion has a slightly distorted square-planar geometry and is coordinated by two N atoms and one O atom from the Schiff base ligand and by an N atom from dicyanamide. The O atoms of water mol-ecules contribute to O-H⋯N, O-H⋯O hydrogen bonds, leading to the formation of sheets parallel to the ac plane. There are also weak inter-actions between inversion-related mol-ecules.

| S-EPMC2915086 | biostudies-literature

A second polymorph of aqua-{4-chloro-2-[(pyridin-2-ylmeth-yl)imino-meth-yl]-phenolato}copper(II) nitrate mono-hydrate.

Project description:The title complex, [Cu(C(13)H(10)ClN(2)O)(H(2)O)]NO(3)·H(2)O, was obtained by the reaction of 5-chloro-salicyl-aldehyde, 2-(amino-meth-yl)pyridine and copper nitrate in methanol. The first reported polymorph of this complex was triclinic [Liang et al. (2010 ?). Acta Cryst. E66, m40]. The present polymorph crystallized in the monoclinic space group P2(1)/c. The Cu(II) ion is in a square planar environment and is coordinated by one phenolate O, one imine N and one pyridine N atom of the tridentate Schiff base ligand and by one water O atom. In the crystal, mol-ecules are linked through inter-molecular O-H?O hydrogen bonds to form chains along the a axis.

| S-EPMC3297234 | biostudies-literature

Bis[4-chloro-2-(imino-meth-yl)phenolato]copper(II).

Project description:In the title mononuclear copper(II) complex, [Cu(C(7)H(5)ClNO)(2)], the Cu atom, situated on an inversion center, is four-coordinated, in a slightly distorted square-planar geometry, by the N- and O-donor atoms of two symmetry-related 4-chloro-2-(imino-meth-yl)phenolate Schiff base ligands.

| S-EPMC2968960 | biostudies-literature

Bis[2-meth-oxy-6-(3-pyridylmethyl-imino-meth-yl)phenolato-?N,O]copper(II).

Project description:In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth-oxy-6-(3-pyridylmethyl-imino-meth-yl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61?(6)° between the planes of the two six-membered rings. The pyridyl ring was refined using a disorder model with approximately 70% occupancy for the major component.

| S-EPMC2980013 | biostudies-literature

Aqua-chloridobis(2-{[3-(morpholin-4-yl)prop-yl]imino-meth-yl}phenolato)manganese(III) monohydrate.

Project description:In the title compound, [Mn(C(14)H(19)N(2)O(2))(2)Cl(H(2)O)]·H(2)O, the Mn(III) atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water mol-ecule in trans positions complete a distorted octa-hedral geometry around the metal atom. In the crystal, the complex mol-ecules and the uncoordinated water mol-ecules are connected via O-H?N, O-H?O and O-H?Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C-H?? inter-actions. The layers are further linked into a three-dimensional network through C-H?O inter-actions.

| S-EPMC3212133 | biostudies-literature

(Azido-κN)[6-meth-oxy-2-(2-pyridylmethyl-imino-meth-yl)phenolato-κN,N',O]copper(II).

Project description:The title compound, [Cu(C(14)H(13)N(2)O(2))(N(3))], is a monomeric neutral complex with one unsymmetrical 6-meth-oxy-2-(2-pyridylmethyl-imino-meth-yl)phenolate Schiff base ligand and one azide ligand. The mol-ecules are connected by a combination of two π-π inter-actions [centroid-centroid distances 3.359 (3) and 3.378 (2) Å] and one C-H⋯N hydrogen bond into a two-dimensional supra-molecular network structure.

| S-EPMC2914922 | biostudies-literature

Bis{4-chloro-2-[(2-hy-droxy-eth-yl)imino-meth-yl]phenolato}nickel(II) monohydrate.

Project description:The title mononuclear nickel(II) complex, [Ni(C(9)H(9)ClNO(2))(2)]·H(2)O, was obtained by the reaction of 5-chloro-salicyl-aldehyde, 2-amino-ethanol and nickel nitrate in methanol. The Ni atom is six-coordinated by two phenolate O, two imine N and two hy-droxy O atoms from two crystallographically different Schiff base ligands, forming an octa-hedral geometry. In the crystal, mol-ecules are linked through inter-molecular O-H⋯O and O-H⋯Cl hydrogen bonds.

| S-EPMC3200802 | biostudies-literature

{4-Chloro-2-[(2-hy-droxy-eth-yl)imino-meth-yl]phenolato}{4-chloro-2-[(2-oxido-eth-yl)imino-meth-yl]phenolato}cobalt(III).

Project description:In the title mononuclear cobalt(III) compound, [Co(C(9)H(8)ClNO(2))(C(9)H(9)ClNO(2))], the Co(II) atom is six-coordinated by two imine N atoms, two phenolate O atoms, and one hy-droxy and one oxide O atom from two Schiff base ligands, forming an octa-hedral geometry. In the crystal structure, adjacent mol-ecules are linked through inter-molecular O-H⋯O hydrogen bonds. The 2-oxidoethyl group is disordered over two positions in a 0.638 (3):0.362 (3) ratio.

| S-EPMC3008055 | biostudies-literature

(2-{[2-Carboxyl-ato-1-(4-chloro-phen-yl)eth-yl]imino-meth-yl}phenolato-?O,N,O')(1H-imidazole-?N)copper(II) monohydrate.

Project description:The Cu(II) atom of the title complex, [Cu(C(16)H(12)ClNO(3))(C(3)H(4)N(2))]·H(2)O, has a distorted square-planar coordination geometry formed by a tridentate Schiff base dianion and an imidazole ligand. The imidazole is nearly coplanar with the coordination plane, the dihedral angle between the planes being 3.73?(12)°. In the Schiff base ligand, the two benzene rings are oriented at a dihedral angle of 75.87?(12)°. O-H?O and N-H?O hydrogen bonding is present in the crystal structure. One H atom of the uncoordinated water mol-ecule is disordered equally over two sites.

| S-EPMC2979152 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data